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91.
The fully biodegradable polymer blends remain challenges for the application due to their undesirable comprehensive performance.Herein,remarkable combination of superior mechanical performance,bacterial resistance,and controllable degradability is realized in the biodegradable poly(L-lactide)/poly(butylene succinate) (PLLA/PBSU) blends by stabilizing the epoxide group modified titanium dioxide nanoparticles (m-TiO2) at the PLLA-PBSU interface through reactive blending.The m-TiO2 can not only act as interfacial compatibilizer but also play the role of photodegradation catalyst:on the one hand,binary grafted nanoparticles were in situ formed and stabilized at the interface to enhance the compatibility between polymer phases.As a consequence,the mechanical properties of the blend,such as the elongation at break,notched impact strength and tensile yield strength,were simultaneously improved.On the other hand,antibacterial and photocatalytic degradation performance of the composite films was synergistically improved,it was found that the m-TiO2 incorporated PLLA/PBSU films exhibit more effective antibacterial activity than the neat PLLA/PBSU films.Moreover,the analysis of photodegradable properties revealed that that m-TiO2 nanoparticles could act as a photocatalyst to accelerate the photodegradation rate of polymers.This study paves a new strategy to fabricate advanced PLLA/PBSU blend materials with excellent mechanical performance,antibacterial and photocatalytic degradation performance,which enables the potential utilization of fully degradable polymers. 相似文献
92.
采用分子动力学模拟方法研究了Al2O3/聚甲基二硅氧烷(PDMS)复合材料在300 K时的传热行为, 通过分析热传导、温度梯度以及导热增强等理论数据, 讨论了不同半径以及不同浓度的Al2O3填料粒子对PDMS传热的影响. 结果表明随着体积分数的增大, Al2O3/PDMS复合材料的热传导先减小后增加. 并且当Al2O3填充粒子的半径为5 nm时, Al2O3/PDMS复合材料的热传导达到最大值. 通过考察传热过程中的Al2O3填料和Al2O3/PDMS复合材料的温度和结构变化, 添加有小半径Al2O3填料的Al2O3/PDMS复合材料在传热的过程中主要以声子的形式进行传热, 此时决定热导率的主要因素有热容c、声子的平均速度v和声子的平均自由程l. 同时, 当体积分数为15%时, 传导链形成, 热量可以顺利通过Al2O3填料形成的传导链传播, 有助于热传导的增加. 相似文献
93.
受限水的介电特性对于石墨烯电容器的储能效率有着重大的影响.因此本文使用分子动力模方法,研究了不同石墨烯纳米孔道宽度(0.812~10 nm)下内受限水介电常数的分布及其影响因素.结果表明,在石墨烯纳米孔道内部受限水双电层结构可分为空隙层、界面层和体相层三个部分.其整体的介电常数随孔道大小的降低而线性减少.这是由内部体相层的宽度的降低而导致的.此外电极电压大小和石墨烯-水相互作用参数εCO的强弱也会显著改变电极表面的双电层(Electric Double Layers, EDLs)结构.其中电压的增大使得介电常数分布的震荡的程度也随之增加,最终导致了整体介电常数的减小.与之类似,亲水态的石墨烯表面(高εCO)下受限水分布的震荡程度也显著增加,这导致了整体介电常数的降低. 相似文献
94.
基于光电倍增管研制了一套无触发信号的双通道光学探测系统, 并组装了测试样机, 实现了对沿面介质阻挡放电(SDBD)等离子体约化电场的测量, 进而通过BOLSIG+软件获得了电子能量. 采用原位紫外吸收光谱和傅里叶变换红外光谱, 研究了SDBD等离子体在不同电压和频率下的化学产物的浓度变化, 并结合空气等离子体化学反应揭示了产物相互作用的微观机理. 结果表明, 电子能量能够改变电子碰撞反应的速率系数, 调控化学反应的源头活性粒子的浓度, 进而影响到化学产物的生成和猝灭. 相似文献
95.
A. D. Matveev 《Journal of Applied Mechanics and Technical Physics》2004,45(3):440-448
This paper considers composites consisting of a set of typical composite multigrid finite elements whose structures are regular and different. Mean local errors are proposed for multigrid modeling of composites. 相似文献
96.
Nanocomposite materials consisting of an epoxy matrix and silicate clay particles have been processed and characterized mechanically.
The clay material used was a modified natural montmorillonite. The clay particles consisted of 1 nm thick layers with aspect
ratios in the range of 100–1000. The clay particles were mixed with acetone and sonicated, then mixed with the polymer, deaerated
and cured. The ultimate objective of processing was to produce a polymer/clay nanocomposite with separated (exfoliated) platelets,
dispersed as uniformly as possible. Samples were prepared with clay concentrations of up to 10 wt%. The process used resulted
in limited exfoliation but mostly intercalation, i.e., infusion of polymer between the silicate layers and increase of interlayer
spacing. The characteristics of the nanocomposite were assessed by transmission electron microscopy and x-ray diffraction.
Results from these observations show that the basal spacing of clay platelets increased from an initial pre-processing value
of 1.85 nm to 4.5 nm. Enhancement of mechanical properties was measured by tensile testing of coupons. Stiffness increases
of up to 50% over that of the unfilled epoxy were measured for clay concentrations of 5 wt%. Strength increases were also
measured for low clay concentrations and low strain rate loading. Micromechanics modeling of mechanical behavior is discussed
as a function of clay platelet dispersion. 相似文献
97.
A PREDICTIVE APPROACH TO THE IN-PLANE MECHANICAL PROPERTIES OF STITCHED COMPOSITE LAMINATES 总被引:1,自引:0,他引:1
Zhang Junqian Wei Yuqing 《Acta Mechanica Solida Sinica》2007,20(2):130-140
This contribution attempts to model the alteration of the in-plane elastic properties in laminates caused by stitching,and to predict the in-plane effective tensile strength of the stitched composite laminates.The distortion of in-plane fibers is considered to be the main cause that affects the in-plane mechanical properties.A fiber distortion model is proposed to characterize the fiber misalignment and the fiber content concentration due to stitching.The undistorted region,the fiber distortion region,the resin-rich pocket and the through-thickness reinforcement section are taken into account.The fiber misalignment and inhomogeneous fiber content due to stitching have been formulated by introducing two parameters,the distortion width and maximum misalignment.It has been found that the ply stress concentration in stitched laminates is influenced by the two concurrent factors,the stitch hole and inhomogeneous fiber content.The stitch hole brings about the stress concentration whereas the higher fiber content at the local region induced by stitching restrains the local deformation of the composite.The model is used to predict the tensile strength of the [0/45/0/-45/90/45/0/-45]_(2s) T300/QY9512 composite laminate stitched by Kevlar 29 yarn with different stitching configurations,showing an acceptable agreement with experimental data. 相似文献
98.
99.
复合材料疲劳Ⅱ型层间裂纹扩展门槛值试验方法研究 总被引:1,自引:0,他引:1
疲劳裂纹扩展门槛值在结构损伤安全设计中具有重要作用,该文提出了复合材料Ⅱ型疲劳裂纹扩展门槛值的试验方法,并实测了两种复合材料的疲劳裂纹扩展门槛值。 相似文献
100.